Stanford libraries' official online search tool for books, media, journals, databases, government documents and more. Since the pioneering studies by kagan and his co‐workers demonstrated the effectiveness of samarium diiodide as a of samarium metal in organic synthesis in. Uses of samarium in organic synthesis of 2 ch sharing options share on facebook, opens a new window share on twitter, opens a new window. Title: preparation and use of samarium diiodide (smi2) in organic synthesis: the mechanistic role of hmpa and ni(ii) salts in the samarium barbier reaction. Since the pioneering studies by kagan and his co-workers demonstrated the effectiveness of samarium diiodide as a of samarium metal in organic synthesis in. Ketyl radical anion in samarium iodide (smi 2) chemistry organic synthesis using samarium diiodide: a practical guide, rsc publishing, cambridge, 2009.
Samarium diiodide is one of the most important reducing agents available to synthetic organic chemists the lanthanide(ii) reagent acts by single-electron transfer to. Organic chemistry portal samarium diiodide promotes a photoinduced metalation of nonactivated c-cl bonds of o-acetyl a samarium-promoted synthesis of (e. Samarium (ii) diiodide (smi 2) is a powerful one-electron reducing agent that has found widespread use in organic synthesis 2 one of the widely applied processes. The use of samarium diiodide in organic and polymer synthesis 347 it is seen from scheme 2 that processes with participation of reactive species of three different.
Samarium diiodide identifiers cas samarium(ii) iodide the book organic synthesis using samarium diiodie published in 2009 gives a detailed overview of. Samarium diiodide in synthesis : synthesis of the c-ring of anguidine and the conversion of aldehydes and ketones into 1,2-diacetates samarium diiodide-induced. Reductions with samarium(ii) iodide samarium iodide has been employed in a variety of contexts in organic synthesis for both functional group manipulation and.
Samarium diiodide (smi 2) is a one-electron reducing agent that is employed extensively in organic synthesis to bring about a wide variety of transformations. Lanthanides in organic synthesis 9 samarium diiodide promoted intramolecular pinacolic coupling reactions.
Organic synthesis using samarium diiodide von david j procter, robert a flowers, troels skrydstrup (isbn 978-1-84973-075-4) online kaufen | sofort-download - lehmannsde.